Di-μ-methanolato-κ4 O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN 2)(nitrato-κO)copper(II)]
نویسندگان
چکیده
Copper nitrate in methanol solution cleaves the N-C(methanol) bond when reacted with 3-methyl-5-phenyl-pyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu(2)(CH(3)O)(2)(NO(3))(2)(C(10)H(10)N(2))(4)], in which the Cu(II) atom is linked to a nitrate ion, two methano-late ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate anion occupies the apical site. The crystal structure features intra-molecular N-H⋯O hydrogen bonds.
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Di-μ-nitrito-κ4 O:O-bis[bis(1-ethyl-1H-imidazole-κN 3)(nitrito-κO)copper(II)]
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